SOLID-STATE POLYMERIZATION OF BIS(TRICHLOROPHENOXO) COBALT(II) COMPLEX TO GIVE POLY(DICHLOROPHENYLENE OXIDE)

被引：23

作者：

BASTURKMEN, M ^{[1
]}

ISCI, H ^{[1
]}

KISAKUREK, D ^{[1
]}

机构：

[1] MIDDLE E TECH UNIV,DEPT CHEM,ANKARA 06531,TURKEY

来源：

POLYMER INTERNATIONAL | 1993年 / 30卷 / 03期

关键词：

POLY(DICHLOROPHENYLENE OXIDE); SOLID STATE POLYMERIZATION; BIS(TRICHLORO-PHENOXO)BIS(PYRIDINE) COBALT(II) COMPLEX; H-1; NMR; C-13; UV-VISIBLE SPECTROPHOTOMETRY;

D O I：

10.1002/pi.4990300319

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Synthesis of four-coordinated (tetrahedral) trichlorophenol cobalt(II) complex with neutral ligand pyridine was achieved from the aqueous solution and its characterization was performed by UV-visible, IR spectral and CHN analysis. Solid state thermal polymerization of the complex was accomplished first at constant temperature employing different time intervals and secondly at constant decomposition time. The poly(dichlorophenylene oxide)s so synthesized were characterized by IR, H-1 NMR and C-13 NMR spectral analysis, T(g) determination, as well as measurement of molecular weight by a viscometric method.

引用

页码：387 / 392

页数：6

共 9 条

[1]

BLANCHARD HS, 1962, J POLYM SCI A2, V58, P469, DOI 10.1002/pol.1962.1205816626

[2] SUBSTITUTED PHENOLS AS LIGANDS .5. 6 COORDINATE COBALT(II) AND NICKEL(II) ADDUCTS WITH NITROGEN BASES AND WATER [J].