PHASE-TRANSITIONS INVOLVING REORDERING OF THE GUEST MOLECULES IN A SOLID ORGANIC INCLUSION COMPOUND - HEPTANOIC ANHYDRIDE-UREA

被引：9

作者：

SHANNON, IJ

HARRIS, KDM

GUILLAUME, F

BOCANEGRA, EH

MACLEAN, EJ

机构：

[1] UNIV BORDEAUX 1, SPECT MOLEC & CRISTALLINE LAB, CNRS, URA 124, F-33405 TALENCE, FRANCE

[2] UNIV BASQUE COUNTRY, FAC CIENCIAS, DEPT FIS APLICADA 2, E-48080 BILBAO, SPAIN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 22期

关键词：

D O I：

10.1039/C39950002341

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Phase transitions below ambient temperature in the heptanoic anhydride-urea inclusion compound have been investigated using X-ray diffraction and differential scanning calorimetry; one of these phase transitions (at ca. 179 K on cooling)is associated with a change in the mode-of three-dimensional ordering of the heptanoic anhydride guest molecules with no detectable change in the host (urea):structure, and represents the first reported example of this type of phase transition for urea inclusion compounds.

引用

收藏

页码：2341 / 2342

页数：2

相关论文

共 15 条

[1] LOW-TEMPERATURE FORM OF UREA ADDUCTS WITH N-PARAFFINS [J].

CHATANI, Y ;

TAKI, Y ;

TADOKORO, H .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1977, 33 (JAN15) :309-311

[2] PHASE-TRANSITION AND STRUCTURE CHANGE OF UREA ADDUCTS WITH N-PARAFFINS AND PARAFFIN-TYPE COMPOUNDS [J].

CHATANI, Y ;

ANRAKU, H ;

TAKI, Y .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1978, 48 (3-4) :219-231

[3] ANHARMONIC VIBRATION OF N-PARAFFIN MOLECULES IN UREA ADDUCTS [J].

FUKAO, K ;

MIYAJI, H ;

ASAI, K .

JOURNAL OF CHEMICAL PHYSICS, 1986, 84 (11) :6360-6368

[4] REPRESENTING AND UNDERSTANDING GEOMETRIC FEATURES OF ONE-DIMENSIONAL TUNNEL STRUCTURES IN SOLID INCLUSION-COMPOUNDS [J].

GEORGE, AR ;

HARRIS, KDM .

JOURNAL OF MOLECULAR GRAPHICS & MODELLING, 1995, 13 (03) :138-141

[5] STRUCTURAL ASPECTS OF UREA INCLUSION-COMPOUNDS AND THEIR INVESTIGATION BY X-RAY-DIFFRACTION - A GENERAL DISCUSSION [J].

HARRIS, KDM ;

THOMAS, JM .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1990, 86 (17) :2985-2996

[6] INVESTIGATING THE STRUCTURE AND DYNAMICS OF A FAMILY OF ORGANIC-SOLIDS - THE ALKANE UREA INCLUSION-COMPOUNDS [J].

HARRIS, KDM .

JOURNAL OF SOLID STATE CHEMISTRY, 1993, 106 (01) :83-98

[7] STRUCTURAL-PROPERTIES OF ALPHA,OMEGA-DIBROMOALKANE UREA INCLUSION-COMPOUNDS - A NEW TYPE OF INTERCHANNEL GUEST MOLECULE ORDERING [J].

HARRIS, KDM ;

SMART, SP ;

HOLLINGSWORTH, MD .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1991, 87 (20) :3423-3429

[8] STRUCTURAL-PROPERTIES OF THE GUEST SPECIES IN DIACYL PEROXIDE UREA INCLUSION-COMPOUNDS - AN X-RAY-DIFFRACTION INVESTIGATION [J].

HARRIS, KDM ;

HOLLINGSWORTH, MD .

PROCEEDINGS OF THE ROYAL SOCIETY-MATHEMATICAL AND PHYSICAL SCIENCES, 1990, 431 (1882) :245-269

[9] POWDER X-RAY-DIFFRACTION STUDIES OF A LOW-TEMPERATURE PHASE-TRANSITION IN THE N-HEXADECANE UREA INCLUSION COMPOUND [J].

HARRIS, KDM ;

GAMESON, I ;

THOMAS, JM .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1990, 86 (18) :3135-3143

[10] COMPARISON OF LENGTHS OF MOLECULES IN UREA AND IN THIOUREA ADDUCTS [J].

LAVES, F ;

NICOLAID.N ;

PENG, KC .

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1965, 121 (2-4) :258-&