SYNTHESIS AND CHARACTERIZATION OF A NOVEL UNSYMMETRICAL METAL-FREE PHTHALOCYANINE WITH DONOR-ACCEPTOR SUBSTITUENTS

被引：32

作者：

LIU, YQ ^{[1
]}

ZHU, DB ^{[1
]}

WADA, T ^{[1
]}

YAMADA, A ^{[1
]}

SASABE, H ^{[1
]}

机构：

[1] INST PHYS & CHEM RES,WAKO,SAITAMA 35101,JAPAN

来源：

JOURNAL OF HETEROCYCLIC CHEMISTRY | 1994年 / 31卷 / 04期

关键词：

D O I：

10.1002/jhet.5570310453

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel unsymmetrical metal-free phthalocyanine with a nitro group as an acceptor substituent and three t-butyl groups as donor groups, namely nitro-tri-t-butylphthalocyanine (NtBuPc) was synthesized for the first time by mixed condensation of two corresponding diiminoisoindolines. The NtBuPc can be separated by common column chromatography on silica gel using chloroform-hexane as the elution solvent. The structure was confirmed by elemental analysis, nmr, uv-vis, ir and mass spectroscopy. No contamination of either symmetrical or other related phthalocyanines was observed.

引用

页码：1017 / 1020

页数：4

共 18 条

[1] ASSOCIATION OF COBALT(II) TETRASULFOPHTHALOCYANINE [J].

ABEL, EW ;

PRATT, JM ;

WHELAN, R .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1976, (06) :509-514

[2] ESR AND ELECTRONIC SPECTRAL INVESTIGATION OF SELF-ASSOCIATION OF PHTHALOCYANINE DYES IN SOLUTION [J].

ABKOWITZ, M ;

MONAHAN, AR .

JOURNAL OF CHEMICAL PHYSICS, 1973, 58 (06) :2281-2287

[3] Phthalocyanines and associated compounds. Part XIV. Further investigations of metallic derivatives. [J].

Barrett, PA ;

Frye, DA ;

Linstead, RP .

JOURNAL OF THE CHEMICAL SOCIETY, 1938, :1157-1163

[4] THERMODYNAMICS OF DIMERIZATION OF COPPER(II) PHTHALOCYANINE-4,4',4'',4'''-TETRASULPHONIC ACID [J].

BLAGROVE, RJ ;

GRUEN, LC .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1973, 26 (01) :225-228

[5]

HALL TW, 1982, NOUV J CHIM, V6, P653

[6] SYNTHESIS AND PROPERTIES OF TERT-BUTYL-SUBSTITUTED VANADYLPHTHALOCYANINE DYES [J].

LAW, KY .

INORGANIC CHEMISTRY, 1985, 24 (12) :1778-1781

[7]

Lever A.P., 1965, ADV INORG CHEM, V7, P27

[8] THE SYNTHESES OF MONOSUBSTITUTED AND DISUBSTITUTED PHTHALOCYANINES USING A DITHIOIMIDE [J].

LEZNOFF, CC ;

GREENBERG, S ;

KHOUW, B ;

LEVER, ABP .

CANADIAN JOURNAL OF CHEMISTRY, 1987, 65 (08) :1705-1713

[9] THE SYNTHESIS OF A SOLUBLE, UNSYMMETRICAL PHTHALOCYANINE ON A POLYMER SUPPORT [J].

LEZNOFF, CC ;

HALL, TW .

TETRAHEDRON LETTERS, 1982, 23 (30) :3023-3026

[10]

LEZNOFF CC, 1989, PHTHALOCYANINES PROP, P8

← 1 2 →