COMPLEXATION OF DIPHENYLZINC WITH SIMPLE ETHERS - CRYSTAL-STRUCTURES OF THE COMPLEXES PH2ZN-BULLET-GLYME AND PH2ZN-BULLET-DIGLYME

被引：24

作者：

MARKIES, PR

SCHAT, G

AKKERMAN, OS

BICKELHAUPT, F

SPEK, AL

机构：

[1] FREE UNIV AMSTERDAM,SCHEIKUNDIG LAB,DE BOELELAAN 1083,1081 HV AMSTERDAM,NETHERLANDS

[2] UNIV UTRECHT,BIJVOET CTR BIOMOLEC RES,VAKGRP KRISTAL & STRUCT CHEM,3584 CH UTRECHT,NETHERLANDS

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 430卷 / 01期

关键词：

D O I：

10.1016/0022-328X(92)80090-K

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complexation behavior of diphenylzinc with a series of mono-, di- and tri-coordinating ethers has been investigated. Two stable crystalline 1:1 adducts, with ethyleneglycol dimethyl ether (glyme) (1) and diethyleneglycol dimethyl ether (diglyme) (2) were isolated and characterized by an X-ray diffraction study. Complex 1 has a normal tetra-coordinated zinc atom; 2 represents the first example of a complex penta-coordinated diorganozinc compound, and has a rather unusual geometry.

引用

页码：1 / 13

页数：13

共 27 条

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