STATIC AND DYNAMIC ELECTROLYTE EFFECTS ON EXCITED LARGE DIPOLE SOLVATION - HIGH DIELECTRIC-CONSTANT SOLVENTS

被引：59

作者：

ITTAH, V

HUPPERT, D

机构：

[1] Raymond and Beverly Sackler, Faculty of Exact Sciences, School of Chemistry, Ramat Aviv

来源：

CHEMICAL PHYSICS LETTERS | 1990年 / 173卷 / 5-6期

关键词：

D O I：

10.1016/0009-2614(90)87242-J

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report on an incresae in the steady-state fluorescence Stokes shift of coumarin 153 when LiClO4 is added to polar solvents. A new relaxation process is observed in the presence of the electrolyte which is realted to the ionic atmosphere relaxation around the large dipole created in the excited state. © 1990.

引用

页码：496 / 502

页数：7

共 31 条

[1]

ACCASCINA F, 1966, RIC SCI, V36, P560

[2] DYNAMICS OF SOLVATION AND CHARGE-TRANSFER REACTIONS IN DIPOLAR LIQUIDS [J].