ACYLOIN CONDENSATION OF ACYCLIC UNSATURATED ALDEHYDES BY MUCOR SPECIES

被引：9

作者：

STUMPF, B

KIESLICH, K

机构：

[1] AG Mikrobielle Stoffumwandlungen, GBF-Gesellschaft für Biotechnologische Forschung mbH, Braunschweig, W-3300

来源：

APPLIED MICROBIOLOGY AND BIOTECHNOLOGY | 1991年 / 34卷 / 05期

关键词：

D O I：

10.1007/BF00167906

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

2E,6Z-Nonadienal, 2E,4E-nonadienal, citral and geraniol as precursors of geranial form acyloins enzymatically by reaction with activated acetate during fermentation by Mucor circinelloides CBS 39468. The acyloins were reduced immediately by the fungus to (2S,3R)-diols. Reduction of the aldehyde group, including hydrogenation of the conjugated C-C double bond, hydroxylation of these alcohols and of the formed diols and some cyclizations are found as side reactions.

引用

页码：598 / 603

页数：6

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