A HIGHLY REGIOSELECTIVE REACTION OF ALLYLIC ACETATES WITH SILYLATED CARBON NUCLEOPHILES DIRECTED BY A SULFENYL GROUP

被引：12

作者：

KUDO, K

SAIGO, K

HASHIMOTO, Y

HOUCHIGAI, H

HASEGAWA, M

机构：

[1] Department of Synthetic Chemistry, Faculty of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 34期

关键词：

D O I：

10.1016/S0040-4039(00)92157-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(alpha-Sulfenylmethyl)allyl acetates reacted with silylated carbon nucleophiles in the presence of a catalytic amount of a Lewis acid to give mainly alpha-adducts at the sulfenylmethyl group in moderate to good yields with high regioselectivity. The reaction may proceed via episulfonium ion intermediates.

引用

收藏

页码：4311 / 4312

页数：2

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