NMR, XRD AND IR STUDY ON MICROCRYSTALLINE OPALS

被引:121
作者
GRAETSCH, H
GIES, H
TOPALOVIC, I
机构
[1] Institut für Mineralogie, Ruhr-Universität Bochum, Bochum, D-44780, Universitätsstrasse 150
关键词
D O I
10.1007/BF00203147
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Microcrystalline opal-CT and opal-C were investigated by Si-29 MAS NMR and Si-29 {H-1} cross polarisation MAS NMR spectroscopy, X-ray small angle scattering, X-ray powder diffraction and infrared absorption spectroscopy. The results are compared with those for non-crystalline precious opal (opal-AG), non-crystalline hyalite (opal-AN), moderately disordered cristobalite and with well ordered low-cristobalite and low-tridymite. Opal-C is confirmed to be strongly stacking disordered low-cristobalite with about 20 to 30% probability for tridymitic stacking. More extensively stacking disordered opal-CT does not contain detectable domains of low-cristobalite or low-tridymite. The stacking sequence is close to 50% cristobalite and 50% tridymitic. The local order decreases with increasing stacking disorder, so that the structural state of microcrystalline opals lies between cristobalite, tridymite and non-crystalline opals.
引用
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页码:166 / 175
页数:10
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