SYNTHESIS AND THERMAL REACTIVITY OF 2-AZIDO-5-TRIMETHYLSILYL-THIOPHENE AND 2-AZIDO-5-METHYLTHIOPHENE - THE PARA-LIKE SUBSTITUENT EFFECT ON FRAGMENTATION OF THE AZIDO GROUP

被引：10

作者：

DAVIES, D ^{[1
]}

SPAGNOLO, P ^{[1
]}

ZANIRATO, P ^{[1
]}

机构：

[1] UNIV BOLOGNA,DIPARTIMENTO CHIM ORGAN A MANGINI,I-40136 BOLOGNA,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1995年 / 06期

关键词：

D O I：

10.1039/p19950000613

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2-Azido-5-trimethylsilylthiophene 1 and 2-azido-5-methylthiophene 2, prepared by azido group transfer of the corresponding heteroaryllithium derivative with toluene-p-sulfonyl azide, show differing chemical reactivity and kinetic behaviour upon 1,3-cycloaddition with the dipolarophile (trimethylsilyl)acetylene and thermal decomposition.

引用

页码：613 / 614

页数：2

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