A NOVEL GALLIUM PHOSPHORUS CAGE COMPOUND

被引：11

作者：

COWLEY, AH ^{[1
]}

JONES, RA ^{[1
]}

MARDONES, MA ^{[1
]}

ATWOOD, JL ^{[1
]}

BOTT, SG ^{[1
]}

机构：

[1] UNIV ALABAMA,DEPT CHEM,TUSCALOOSA,AL 35486

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 09期

关键词：

D O I：

10.1002/anie.199111411

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The tBuGaCl2 unit of the Ga3P4 cage compound 1 behaves simultaneously as a Lewis acid and a Lewis base. In this formal approach the lone electron pairs of two phosphorus atoms stabilize the Lewis acidic gallium atom of this unit and two chloro bridges stemming from it stabilize the Lewis acidic gallium atoms of the tBuGa(PtBu)2 units. The compound 1 is accessible from tBuGaCl2 and K2[tBuPPtBu]. [GRAPHICS]

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页码：1141 / 1143

页数：3

相关论文

共 8 条

[1] CONTRIBUTIONS TO THE CHEMISTRY OF PHOSPHORUS .101. SYNTHESIS AND PROPERTIES OF DIPHOSPHABORIRANES (TERT-BUP)2BNR2 AND (TERT-BUP)2BNR1R2 [J].

BAUDLER, M ;

MARX, A .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1981, 474 (03) :18-30

[2] CONTRIBUTIONS TO CHEMISTRY OF PHOSPHORUS .79. ABOUT RING CLEAVAGE OF TETRA-TERT-BUTYL-CYCLOTETRAPHOSPHANE BY POTASSIUM AND SULFUR [J].

BAUDLER, M ;

GRUNER, C ;

FURSTENBERG, G ;

KLOTH, B ;

SAYKOWSKI, F ;

OZER, U .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1978, 446 (NOV) :169-176

[3] CONTRIBUTIONS TO CHEMISTRY OF PHOSPHORUS .80. ABOUT PHOSPHORUS BORON 3-MEMBERED RING COMPOUND (TERT-BUP)2BN(I-PR)2 [J].

BAUDLER, M ;

MARX, A ;

HAHN, J .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1978, 33 (04) :355-360

[4]

Cowley A.H., 1989, ANGEW CHEM, V101, P1235

[5]

Cowley A. H., 1991, HETEROATOM CHEM, V2, P11, DOI [10.1002/HC.520020103, DOI 10.1002/HC.520020103]

[6] SINGLE-SOURCE III/V PRECURSORS - A NEW APPROACH TO GALLIUM-ARSENIDE AND RELATED SEMICONDUCTORS [J].

COWLEY, AH ;

JONES, RA .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (09) :1208-1215

[7] STRUCTURAL CHEMISTRY OF PHOSPHORUS-CONTAINING CHAINS AND RINGS .2. CRYSTAL AND MOLECULAR-STRUCTURE OF THE DIPHOSPHABORIRANE (TERT-BUP)2BNET2 [J].

FEHER, M ;

FROHLICH, R ;

TEBBE, KF .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1981, 474 (03) :31-42

[8] AZABOROLINYL COMPLEXES .27. TITANIUM AND VANADIUM CHLORIDE COMPLEXES WITH DIAZABORETIDINE AND 1,2-AZABOROLINYL LIGANDS [J].

SCHMID, G ;

KAMPMANN, D ;

MEYER, W ;

BOESE, R ;

PAETZOLD, P ;

DELPY, K .

CHEMISCHE BERICHTE-RECUEIL, 1985, 118 (06) :2418-2428