1ST BARIUM OXOMERCURATE - SYNTHESIS AND CRYSTAL-STRUCTURE

被引：19

作者：

SOLL, M

MULLERBUSCHBAUM, H

机构：

[1] Institut für Anorganische Chemie der Christian-Albrechts-Universität, D-2300 Kiel

来源：

JOURNAL OF THE LESS-COMMON METALS | 1990年 / 162卷 / 01期

关键词：

D O I：

10.1016/0022-5088(90)90471-U

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

BaHgO2 was prepared for the first time by an oxygen-high pressure technique. X-ray investigations of single crystals indicate a hexagonal symmetry, space group D66 - P6322 (No. 182); a = 6.904; c = 11.970 A ̊; Z = 6. Hg2+ is coordinated by two oxygen ions and Ba2+ by six oxygen ions. Two-dimensional layers of trigonal BaO6 prisms are connected by O-Hg-O dumb bells along [001]. © 1990.

引用

页码：169 / 174

页数：6