MATHEMATICAL REPRESENTATION OF THERMODYNAMIC PROPERTIES .2. DERIVATION OF THE COMBINED NEARLY IDEAL BINARY SOLVENT (NIBS) REDLICH-KISTER MATHEMATICAL REPRESENTATION FROM A 2-BODY AND 3-BODY INTERACTIONAL MIXING MODEL

被引：564

作者：

ACREE, WE

机构：

[1] Department of Chemistry, University of North Texas, Denton

来源：

THERMOCHIMICA ACTA | 1992年 / 198卷 / 01期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0040-6031(92)85059-5

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

A relatively simple two-body and three-body interactional mixing model is used to derive expressions for the mathematical representation of experimental solute solubilities and activity coefficients in binary solvent mixtures. The derived expressions are identical with those based upon the combined NIBS/Redlich-Kister model, and enable solute solubility/activity coefficient data to be expressed as a mole fraction average of measured solute properties in both pure solvents plus a term involving a power series expansion in solvent composition.

引用

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页码：71 / 79

页数：9

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