THE PREPARATION AND CHARACTERIZATION OF THE PARAMAGNETIC SOLID BIS(1,2,3,4-TRITHIAZOLIUM)BIS(HEXAFLUOROARSENATE) CONTAINING THE DIOXYGEN-LIKE DICATION DIRADICAL .+SSSNCCNSSS+.

被引：29

作者：

BOYLE, PD

PARSONS, S

PASSMORE, J

WOOD, DJ

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 02期

关键词：

D O I：

10.1039/c39930000199

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hexafluoroarsenate salt of .+SSSNCCNSSS+.1, prepared by the reaction of S8(AsF6)2, S4(AsF6)2 and (CN)2 in SO2, is the only known sterically unhindered non-metal diradical, other than dioxygen, that contains two unpaired electrons in the solid state (mu = 2.81 mu(B) at room temp.).

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页码：199 / 201

页数：3

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