A NEW ACTIVE CATALYST SPECIES FOR ENANTIOSELECTIVE ALKYLATION BY PHASE-TRANSFER CATALYSIS

被引：221

作者：

ODONNELL, MJ ^{[1
]}

WU, SD ^{[1
]}

HUFFMAN, JC ^{[1
]}

机构：

[1] INDIANA UNIV, DEPT CHEM, BLOOMINGTON, IN 47405 USA

来源：

TETRAHEDRON | 1994年 / 50卷 / 15期

关键词：

D O I：

10.1016/S0040-4020(01)89382-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This paper briefly reviews the use of Schiff base substrates in amino acid synthesis. Recent studies lead to the proposal of a new active catalyst species (12) for the asymmetric PTC alkylation of active methylene compounds (2). Mechanistic implications are detailed.

引用

页码：4507 / 4518

页数：12

共 77 条

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