KINETIC-STUDY OF ION-TRANSPORT FACILITATED BY CROWN ETHERS ACROSS WATER NITROBENZENE INTERFACE

被引：24

作者：

SENO, M

IWAMOTO, K

CHEN, QZ

机构：

[1] Institute of Industrial Science, University of Tokyo, Minato-Ku, Tokyo, 106

来源：

ELECTROCHIMICA ACTA | 1990年 / 35卷 / 01期

关键词：

D O I：

10.1016/0013-4686(90)85049-S

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The thermodynamic and kinetic behaviours of alkali metal ion transfer facilitated by some crown ethers (18-crown-6, dibenzo-18-crown-6, dibenzo-24-crown-8) from water to nitrobenzene were studied by means of cyclic voltammetry and impedance measurement. The results indicate that each crown ether forms complexes with the respective alkali metal cations, of which stability constants are dependent on the sort of crown ethers and alkali metal cations. Moreover, the potential dependence of the rate constant of the facilitated ion transfer is sensitive to the stability constant in the nitrobenzene phase. © 1990.

引用

页码：127 / 134

页数：8

共 21 条

[1] CHRONOPOTENTIOMETRIC INVESTIGATION OF DIFFUSION OVERVOLTAGE AT INTERFACE BETWEEN 2 NON-MISCIBLE SOLUTIONS .1. AQUEOUS SOLUTION-TETRABUTYLAMMONIUM ION SPECIFIC LIQUID MEMBRANE
GAVACH, C
HENRY, F
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1974, 54 (02): : 361 - 370
[2] HIRAOKA M, 1978, CROWN COMPOUNDS THEI, P84
[3] THE TRANSFER OF ALKALI-METAL IONS ACROSS THE WATER-NITROBENZENE INTERFACE FACILITATED BY NEUTRAL MACROCYCLIC IONOPHORES
HOFMANOVA, A
HUNG, LQ
KHALIL, W
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1982, 135 (02) : 257 - 264
[4] FARADAIC ION TRANSFER ACROSS THE INTERFACE OF 2 IMMISCIBLE ELECTROLYTE-SOLUTIONS - CHRONOPOTENTIOMETRY AND CYCLIC VOLTAMMETRY
HOMOLKA, D
HUNG, LQ
HOFMANOVA, A
KHALIL, MW
KORYTA, J
MARECEK, V
SAMEC, Z
SEN, SK
VANYSEK, P
WEBER, J
BREZINA, M
JANDA, M
STIBOR, I
[J]. ANALYTICAL CHEMISTRY, 1980, 52 (11) : 1606 - 1610
[5] ON THE MECHANISM OF TRANSFER OF SODIUM-ION ACROSS THE NITROBENZENE WATER INTERFACE FACILITATED BY DIBENZO-18-CROWN-6
KAKUTANI, T
NISHIWAKI, Y
OSAKAI, T
SENDA, M
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1986, 59 (03) : 781 - 788
[6] POTASSIUM-ION TRANSFER ACROSS THE NITROBENZENE WATER INTERFACE FACILITATED BY VALINOMYCIN
KORYTA, J
KOZLOV, YN
SKALICKY, M
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1987, 234 (1-2) : 355 - 360
[7] ELECTROCHEMICAL POLARIZATION PHENOMENA AT THE INTERFACE OF 2 IMMISCIBLE ELECTROLYTE-SOLUTIONS
KORYTA, J
[J]. ELECTROCHIMICA ACTA, 1979, 24 (03) : 293 - 300
[8] KORYTA J, 1983, ION SEL ELECTRODE R, V5, P131
[9] SYSTEMATIC STUDY OF THE EFFECT OF MACROCYLE RING SIZE AND DONOR ATOM TYPE ON THE LOG-K, DELTA-H, AND T-DELTA-S OF REACTIONS AT 25-DEGREES-C IN METHANOL OF MONO-VALENT AND DIVALENT-CATIONS WITH CROWN ETHERS
LAMB, JD
IZATT, RM
SWAIN, CS
CHRISTENSEN, JJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (02) : 475 - 479
[10] LIN S, 1985, J ELECTROANAL CHEM, V191, P437

← 1 2 3 →