PORPHYRIN-CYCLOPHANES - INCLUSION COMPLEXATION AND X-RAY CRYSTAL-STRUCTURE OF A ZINC OCTAMETHYLDIPHENYLPORPHYRIN

被引:24
作者
BENSON, DR [1 ]
VALENTEKOVICH, R [1 ]
KNOBLER, CB [1 ]
DIEDERICH, F [1 ]
机构
[1] UNIV CALIF LOS ANGELES,DEPT CHEM & BIOCHEM,LOS ANGELES,CA 90024
关键词
D O I
10.1016/S0040-4020(01)81777-4
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The synthesis, characterization, and complexation properties of two novel porphyrincyclophanes are reported. In the first system, one face of an octamethyldiphenylporphyrin is capped by one diphenylmethane unit. In the second system, both faces of a tetraphenylporphyrin are strapped by diphenylmethane units. The X-ray crystal structure has been determined for the singly-capped zinc octamethyldiphenylporphyrin.
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页码:2401 / 2422
页数:22
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