CATALYTIC ACTIVITY OF CLUSTER RUTHENIUM COMPLEXES - OLIGOMERIZATION OF ETHYLENE

被引：6

作者：

BIANCHI, M

MENCHI, G

MATTEOLI, U

PIACENTI, F

机构：

[1] UNIV FLORENCE,DEPT ORGAN CHEM,VIA G CAPPONI 9,I-50121 FLORENCE,ITALY

[2] UNIV VENICE,DEPT CHEM,I-30123 VENICE,ITALY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 451卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)83018-Q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Ru3(CO)12], one of a series of ruthenium carbonyls tested, shows good catalytic activity in the oligomerization of ethylene in several organic solvents at temperatures above 80-degrees-C and olefin pressures exceeding 5 atm. Olefin conversions up to 90% are reached. C4-C-12 olefins are the main reaction products, with Prevalence of the C4 species. Branched isomers are prevalent among the higher oligomers. Evidence has been obtained for a key role for ruthenium hydride intermediates in this catalytic cycle.

引用

收藏

页码：139 / 146

页数：8

相关论文

共 47 条

[1] DI-MU-CARBONYL-TRIS(CYCLOPENTADIENYLNICKEL) AS A CLUSTER PRECURSOR TO A HIGHLY-ACTIVE ETHYLENE OLIGOMERIZATION CATALYST [J].

BEACH, DL ;

KOBYLINSKI, TP .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1980, (19) :933-934

[2]

BEACH DL, 1981, Patent No. 4293726

[3]

BEHR A, 1986, ISRAEL J CHEM, V27, P277

[4]

BIANCHI M, 1981, CHIM IND-MILAN, V63, P475

[5] HYDROFORMYLATION OF OLEFINS IN THE PRESENCE OF RUTHENIUM CATALYSTS [J].

BIANCHI, M ;

MENCHI, G ;

FREDIANI, P ;

MATTEOLI, U ;

PIACENTI, F .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 247 (01) :89-94

[6] ASYMMETRIC-SYNTHESIS BY CHIRAL RUTHENIUM COMPLEXES .9. THE ROLE OF ISOMERIZATION IN THE ASYMMETRIC HYDROGENATION OF PHENYLBUTENES CATALYZED BY H4RU4(CO)8[(-)-DIOP]2 [J].

BIANCHI, M ;

MATTEOLI, U ;

FREDIANI, P ;

MENCHI, G ;

PIACENTI, F ;

BOTTEGHI, C ;

MARCHETTI, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 252 (03) :317-325

[7] HOMOGENEOUS CATALYTIC-HYDROGENATION OF FREE CARBOXYLIC-ACIDS IN THE PRESENCE OF CLUSTER RUTHENIUM CARBONYL HYDRIDES [J].

BIANCHI, M ;

MENCHI, G ;

FRANCALANCI, F ;

PIACENTI, F ;

MATTEOLI, U ;

FREDIANI, P ;

BOTTEGHI, C .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 188 (01) :109-119

[8] [RUH(1-6-ETA-C8H10)(1',2'-5',6'-ETA-C8H12)]BF4, THE 1ST ISOLATED HYDRIDOMETAL COMPLEX STABILIZED ONLY BY ALICYCLIC HYDROCARBON LIGANDS AND A VERY EFFICIENT CATALYST PRECURSOR FOR THE TRANSFORMATION OF ALKENES [J].

BOUACHIR, F ;

CHAUDRET, B ;

TKATCHENKO, I .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (02) :94-96

[9]

BRACA G, 1969, CHIM IND-MILAN, V51, P1245

[10]

BRACA G, 1968, CHIM IND-MILAN, V50, P121

← 1 2 3 4 5 →