REDUCTIVE DESULFONYLATION OF PHENYL SULFONES BY SAMARIUM(II) IODIDE-HEXAMETHYLPHOSPHORIC TRIAMIDE

被引：74

作者：

KUNZER, H

STAHNKE, M

SAUER, G

WIECHERT, R

机构：

[1] Research Laboratories, Schering AG Berlin, 1000 Berlin 65

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 17期

关键词：

D O I：

10.1016/0040-4039(91)85009-T

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Samarium(II) iodide in tetrahydrofuran reductively desulfonylates phenyl sulfones in the presence of hexamethylphosphoric triamide. This transformation is illustrated here for ten substrates, which include secondary alicyclic, beta-hydroxy, vicinal bis-, and alpha,beta-unsaturated sulfones.

引用

页码：1949 / 1952

页数：4

共 28 条

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