REDUCTIVE DESULFONYLATION OF PHENYL SULFONES BY SAMARIUM(II) IODIDE-HEXAMETHYLPHOSPHORIC TRIAMIDE

被引:74
作者
KUNZER, H
STAHNKE, M
SAUER, G
WIECHERT, R
机构
[1] Research Laboratories, Schering AG Berlin, 1000 Berlin 65
关键词
D O I
10.1016/0040-4039(91)85009-T
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Samarium(II) iodide in tetrahydrofuran reductively desulfonylates phenyl sulfones in the presence of hexamethylphosphoric triamide. This transformation is illustrated here for ten substrates, which include secondary alicyclic, beta-hydroxy, vicinal bis-, and alpha,beta-unsaturated sulfones.
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页码:1949 / 1952
页数:4
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