TRANSITION-METAL COMPLEXES OF LOWER RIM 1,3-DIPHOSPHINITE AND 1,3-DIPHOSPHINO CALIX[4]ARENES

被引:29
作者
CAMERON, BR [1 ]
VANVEGGEL, FCJM [1 ]
REINHOUDT, DN [1 ]
机构
[1] UNIV TWENTE,ORGAN CHEM LAB,7500 AE ENSCHEDE,NETHERLANDS
关键词
D O I
10.1021/jo00114a032
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
5,11,17,23-Tetra-tert-butyl-25,27-bis((diphenylphosphino)oxy)-26,28-dipropoxycalix[4]arene, 3, is easily prepared from chlorodiphenylphosphine and 1,3-dipropoxycalix[4]arene in exclusively the cone conformation. 5,11,17,23-Tetra-tert-butyl-25,27-bis((diphenylphosphino)ethoxy)-26,28-dipro poxycalix[4]arene, 5 (also in the cone conformation), is obtained from the reaction of KPPh(2) with the 1,3-ditosylate calix[4]arene derivative. The coordination properties of calix[4]arene ligands 3 and 5 with Rh-I, Cu-I, and Pt-II have been investigated. Isolation of both bimetallic (Rh-2(3)(COD)(2)Cl-2) and monometallic (Rh(3(P=O))(COD)CI) complexes proved that the ligand binds to the Rh-I ion in a monodentate fashion. However, in the case of the Cu-I complex, a bidentate coordination is observed. Compound 5 coordinates to both Cu-I and Pt-II in a bidentate fashion, in which the two phosphorus atoms coordinate in a cis arrangement to the Pt-II center.
引用
收藏
页码:2802 / 2806
页数:5
相关论文
共 53 条
  • [1] PROXIMAL INTRAANNULAR MODIFICATIONS OF CALIX[4]ARENE VIA ITS SPIRODIENONE DERIVATIVE
    ALEKSIUK, O
    GRYNSZPAN, F
    BIALI, SE
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (01) : 11 - 13
  • [2] BIS(BENZONITRILE)DICHLORO COMPLEXES OF PALLADIUM AND PLATINUM
    ANDERSON, GK
    LIN, M
    [J]. INORGANIC SYNTHESES, 1990, 28 : 60 - 63
  • [3] New artificial receptors from selectively functionalized calix[4]arenes
    Arduini, Arturo
    Casnati, Alessandro
    Fabbi, Massimo
    Minari, Patrizia
    Pochini, Andrea
    Sicuri, Anna Rita
    Ungaro, Rocco
    [J]. SUPRAMOLECULAR CHEMISTRY, 1993, 1 (3-4) : 235 - 246
  • [4] CATION COMPLEXATION BY CHEMICALLY-MODIFIED CALIXARENES .5. PROTONATION CONSTANTS FOR CALIXARENE CARBOXYLATES AND STABILITY-CONSTANTS OF THEIR ALKALI AND ALKALINE-EARTH COMPLEXES
    ARNAUDNEU, F
    BARRETT, G
    HARRIS, SJ
    OWENS, M
    MCKERVEY, MA
    SCHWINGWEILL, MJ
    SCHWINTE, P
    [J]. INORGANIC CHEMISTRY, 1993, 32 (12) : 2644 - 2650
  • [5] SYNTHESIS, X-RAY CRYSTAL-STRUCTURES, AND CATION-BINDING PROPERTIES OF ALKYL CALIXARYL ESTERS AND KETONES, A NEW FAMILY OF MACROCYCLIC MOLECULAR RECEPTORS
    ARNAUDNEU, F
    COLLINS, EM
    DEASY, M
    FERGUSON, G
    HARRIS, SJ
    KAITNER, B
    LOUGH, AJ
    MCKERVEY, MA
    MARQUES, E
    RUHL, BL
    SCHWINGWEILL, MJ
    SEWARD, EM
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (23) : 8681 - 8691
  • [6] ASFARI Z, 1994, J ORG CHEM, V59, P1741
  • [7] CALIXARENES AS 2ND-SPHERE LIGANDS FOR TRANSITION-METAL IONS - SYNTHESIS AND CRYSTAL-STRUCTURE OF [(H2O)5NI(NC5H5)]2(NA)[CALIX[4]ARENE SULFONATE].3.5H2O AND [(H2O)4CU(NC5H5)2]-(H3O)3 [CALIX[4]ARENE SULFONATE].10 H2O
    ATWOOD, JL
    ORR, GW
    HAMADA, F
    VINCENT, RL
    BOTT, SG
    ROBINSON, KD
    [J]. JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY, 1992, 14 (01): : 37 - 46
  • [8] ATWOOD JL, 1993, SUPRAMOL CHEM, V2, P309
  • [9] ATWOOD JL, 1991, J AM CHEM SOC, V113, P2761
  • [10] SELECTIVE ELECTROCHEMICAL RECOGNITION OF THE DIHYDROGEN PHOSPHATE ANION IN THE PRESENCE OF HYDROGEN SULFATE AND CHLORIDE-IONS BY NEW NEUTRAL FERROCENE ANION RECEPTORS
    BEER, PD
    CHEN, Z
    GOULDEN, AJ
    GRAYDON, A
    STOKES, SE
    WEAR, T
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (24) : 1834 - 1836