FEMTOSECOND PHOTOASSOCIATION SPECTROSCOPY - COHERENT BOND FORMATION

被引：76

作者：

MARVET, U ^{[1
]}

DANTUS, M ^{[1
]}

机构：

[1] MICHIGAN STATE UNIV,CTR FUNDAMENTAL MAT RES,E LANSING,MI 48824

来源：

CHEMICAL PHYSICS LETTERS | 1995年 / 245卷 / 4-5期

关键词：

D O I：

10.1016/0009-2614(95)01018-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The method femtosecond photoassociation spectroscopy (FPAS) is introduced and we report on its application to the study of the reaction Hg + Hg + h nu --> Hg-2. Our results demonstrate coherent bond formation obtained in the femtosecond time scale from free unbound reactants. The product Hg-2 is formed in the D1(u) state and shows a high degree of rotational anisotropy induced by the polarization of the binding femtosecond pulse.

引用

页码：393 / 399

页数：7

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