GAS-PHASE INORGANIC-CHEMISTRY - LASER SPECTROSCOPY OF CALCIUM AND STRONTIUM MONOFORMAMIDATES

被引：7

作者：

BOPEGEDERA, AMRP ^{[1
]}

FERNANDO, WTML ^{[1
]}

BERNATH, PF ^{[1
]}

机构：

[1] UNIV ARIZONA,DEPT CHEM,TUCSON,AZ 85721

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1990年 / 94卷 / 09期

关键词：

D O I：

10.1021/j100372a035

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reaction products of calcium and strontium metal vapors with formamide were studied by using laser spectroscopic techniques. Three electronic transitions were observed for the resulting metal monoformamidates, MNHCOH. The formamidate ligand is probably bonding to the metal in a bidentate manner. The metal-ligand stretching vibrational frequencies were assigned from the low-resolution spectra. © 1990 American Chemical Society.

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页码：3547 / 3549

页数：3

相关论文

共 20 条

[1] ABINITIO CALCULATION OF POTENTIAL-ENERGY SURFACE AND GEOMETRIC STRUCTURE OF LIBH4 NON-RIGID COMPLEX MOLECULE [J].

BOLDYREV, AI ;

CHARKIN, OP ;

RAMBIDI, NG ;

AVDEEV, VI .

CHEMICAL PHYSICS LETTERS, 1976, 44 (01) :20-24

[2] ROTATIONAL ANALYSIS OF THE A2-PI-X2-SIGMA+ TRANSITION OF CALCIUM MONOACETYLIDE, CACCH [J].

BOPEGEDERA, AMRP ;

BRAZIER, CR ;

BERNATH, PF .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1988, 129 (02) :268-275

[3] LASER SPECTROSCOPY OF CALCIUM AND STRONTIUM MONOACETYLIDES [J].

BOPEGEDERA, AMRP ;

BRAZIER, CR ;

BERNATH, PF .

CHEMICAL PHYSICS LETTERS, 1987, 136 (01) :97-100

[4] LASER SPECTROSCOPY OF STRONTIUM AND CALCIUM MONOALKYLAMIDES [J].

BOPEGEDERA, AMRP ;

BRAZIER, CR ;

BERNATH, PF .

JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (11) :2779-2781

[5] LASER SPECTROSCOPY OF ORGANOMETALLIC FREE-RADICALS [J].

BRAZIER, CR ;

BERNATH, PF ;

KINSEYNIELSEN, S ;

ELLINGBOE, LC .

JOURNAL OF CHEMICAL PHYSICS, 1985, 82 (02) :1043-1045

[6] THE A2E-X2A1 TRANSITION OF MONOMETHYL CALCIUM - A ROTATIONAL ANALYSIS [J].

BRAZIER, CR ;

BERNATH, PF .

JOURNAL OF CHEMICAL PHYSICS, 1989, 91 (08) :4548-4554

[7] OBSERVATION OF GAS-PHASE ORGANOMETALLIC FREE-RADICALS - MONOMETHYL DERIVATIVES OF CALCIUM AND STRONTIUM [J].

BRAZIER, CR ;

BERNATH, PF .

JOURNAL OF CHEMICAL PHYSICS, 1987, 86 (11) :5918-5922

[8] LASER SPECTROSCOPY OF ALKALINE-EARTH MONOALKOXIDE FREE-RADICALS [J].

BRAZIER, CR ;

ELLINGBOE, LC ;

KINSEYNIELSEN, S ;

BERNATH, PF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (09) :2126-2132

[9] LASER SPECTROSCOPY OF CALCIUM AND STRONTIUM MONOAZIDE FREE-RADICALS [J].

BRAZIER, CR ;

BERNATH, PF .

JOURNAL OF CHEMICAL PHYSICS, 1988, 88 (04) :2112-2116

[10]

BRAZIER CR, UNPUB