ROTATIONAL STATE DEPENDENCE OF THE PREDISSOCIATION DYNAMICS IN H2O, D2O (C(B-1)1 AND B(A-1)1)

被引：4

作者：

HODGSON, A ^{[1
]}

SIMONS, JP ^{[1
]}

ASHFOLD, MNR ^{[1
]}

BAYLEY, JM ^{[1
]}

DIXON, RN ^{[1
]}

机构：

[1] UNIV BRISTOL,SCH CHEM,BRISTOL BS8 1TS,AVON,ENGLAND

来源：

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 1985年 / 89卷 / 03期

关键词：

Physical chemistry - Spectroscopy; Ultraviolet;

D O I：

10.1002/bbpc.19850890311

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The two photon photodissociation of H//2O, D//2O (C**1B//1) from individually selected J prime (Ka prime Kc prime ) rotational levels in the (000) vibrational level has been investigated experimentally using a line-narrowed, tunable KrF laser. The results establish a strong dependence on the magnitude of LT AN BR Ja prime **2 RT AN BR ** one-half congruent Ka prime , both for the heterogeneous predissociation path and for the subsequent branching on the B**1A//1 potential at the Renner-Teller intersection with A**1B//1 near linearity.

引用

页码：251 / 254

页数：4

共 15 条

[1] NUCLEAR AND ELECTRON DYNAMICS IN THE PHOTODISSOCIATION OF WATER [J].