THE 3-NU(1)+NU(3) VIBRATIONAL OVERTONE SPECTRUM OF (CH4)-C-13

被引：8

作者：

BORAAS, K

REILLY, JP

机构：

[1] Department of Chemistry, Indiana University, Bloomington, IN

来源：

CHEMICAL PHYSICS | 1995年 / 190卷 / 2-3期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0301-0104(94)00314-Z

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The 3 nu(1) + nu(3) vibrational overtone spectrum of (CH4)-C-13 is recorded under Doppler-limited resolution conditions using a titanium sapphire laser-based photoacoustic spectrometer. Data at two temperatures, 100 and 293 K, are presented. The observed spectral congestion is qualitatively similar to that observed for (CH4)-C-12, but the detailed re-vibrational structure of the two isotope variants is completely different. The data reflect the complicating influences of tetrahedral fine structure and vibrational state mixing.

引用

页码：301 / 309

页数：9

共 24 条

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