SYNTHESIS AND ABSORPTION EMISSION SPECTRAL PROPERTIES OF STYRYLSTILBENE AND DISTYRYLANTHRACENE DERIVATIVES

被引：63

作者：

NAKATSUJI, S ^{[1
]}

MATSUDA, K ^{[1
]}

UESUGI, Y ^{[1
]}

NAKASHIMA, K ^{[1
]}

AKIYAMA, S ^{[1
]}

KATZER, G ^{[1
]}

FABIAN, W ^{[1
]}

机构：

[1] GRAZ UNIV,INST ORGAN CHEM,A-8010 GRAZ,AUSTRIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1991年 / 06期

关键词：

D O I：

10.1039/p29910000861

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of para-substituted styrylstilbenes I and 9,10-distyrylanthracenes II was synthesized by Wittig or Arbusov-Horner reaction as a key step. Subsequently, systematic investigations were carried out on their absorption and fluorescence spectra, and their chemiluminescence properties. It has become apparent that substituent effects are present in each pi-electron system. Pariser-Parr-Pople self-consistent field configurational interaction molecular orbital (PPP-SCF-CI-MO) calculations on some representatives of each series I and II were put into practice by considering the geometry of excited states, and the values obtained were well correlated with the experimental results.

引用

页码：861 / 867

页数：7

共 29 条

[1] FLUORESCENCE-SPECTRA CHARACTERISTICS OF ALPHA,OMEGA-DI-1-ANTHRYLPOLY-YNES AND 9-ANTHRYLPOLY-YNES [J].