UNEXPECTED FORMATION OF A FLYOVER-BRIDGED COMPLEX BY REACTION OF A FERROLE DERIVATIVE WITH PH2PCH2PPH2 (DPPM) AND ME3NO - CRYSTAL-STRUCTURE OF [FE2(CO)5(P-DPPM)(C2ET2(CO)C2ET2)]

被引：11

作者：

GIORDANO, R ^{[1
]}

SAPPA, E ^{[1
]}

CAUZZI, D ^{[1
]}

PREDIERI, G ^{[1
]}

TIRIPICCHIO, A ^{[1
]}

CAMELLINI, MT ^{[1
]}

机构：

[1] UNIV PARMA,CNR,CTR STUDIO STRUTTURIST DIFFRATTOMETR,IST CHIM GEN INORGAN,I-43100 PARMA,ITALY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 412卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(91)86068-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of the ''ferrole'' complex [Fe2(CO)6(C2Et2)2] with Ph2PCH2PPh2 (dppm), in the presence of Me3NO, affords as major product the ''flyover-bridged'' derivative [Fe2(CO)5(P-dppm){C2Et2(CO)C2Et2}], apparently produced via CO insertion into the central carbon-carbon single bond of the original ligand. Its structure has been determined by an X-ray diffraction study. Simple CO substitution on the intact ferrole also occurs, as a minor process.

引用

页码：C14 / C18

页数：5

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