SYNTHESES AND STRUCTURES OF CYCLIC AND ACYCLIC COMPOUNDS CONTAINING VANADIUM(V) AND MOLYBDENUM(VI)

被引：15

作者：

OLMS, P ^{[1
]}

ROESKY, HW ^{[1
]}

KELLER, K ^{[1
]}

NOLTEMEYER, M ^{[1
]}

BOHRA, R ^{[1
]}

SCHMIDT, HG ^{[1
]}

STALKE, D ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,TAMANNSTR 4,W-3400 GOTTINGEN,GERMANY

来源：

CHEMISCHE BERICHTE-RECUEIL | 1991年 / 124卷 / 12期

关键词：

METALLACYCLIC SYSTEMS; VANADIUM; MOLYBDENUM;

D O I：

10.1002/cber.19911241204

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of (C2F5)2P(Cl) = NSiMe3 (2) with Cl3V = NSiMe3 in CH2Cl2 yields the eight-membered ring [(C2F5)2PN2VCl2]2 (3). (CF3)2P(Cl) = NSiMe3 (1) reacts with VOCl3 to form the eight-membered ring [(CF3)2PN]3NVCl2 (4). A six-membered ring [Ph2PN]2NVCl2 (5) can be isolated from the reaction of Ph2P(Cl) = NSiMe3 with VOCl3. 1 reacts quantitatively with MoO2Cl2 and MoOCl4 to form [MoOCl3-O-P(CF3)2 = NSiMe3]4 (6) and (CF3)2P(Cl) = N-MoOCl3 (7), respectively. The molecular structures of 3, 5, and 6 have been determined by X-ray diffraction.

引用

页码：2655 / 2661

页数：7

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