MOLECULAR VIBRATION ANALYSIS OF IONICITY AND PHASE-TRANSITION IN TMPD-TCNQ (1-1) CHARGE-TRANSFER SALT

被引：32

作者：

GIRLANDO, A

PAINELLI, A

PECILE, C

机构：

[1] Inst of Physical Chemistry, Padua, Italy, Inst of Physical Chemistry, Padua, Italy

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1984年 / 112卷 / 3-4期

关键词：

VIBRATIONS - Spectrum Analysis;

D O I：

10.1080/00268948408071843

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The infrared spectra of the (1:1) charge transfer salt of N, N, N prime , N prime -tetramethyl-p-phenylendiamine (TMPD) with 7, 7, 8, 8-tetracyanoquinodimethane (TCNQ) and with fully deuterated TCNQ are reported. The assignment of the vibrational data is obtained on the basis of the comparison with that of neutral and ionized parent molecules; additional relevant information is extracted from the low temperature (approximately 15 K) infrared and Raman spectra.

引用

页码：325 / 343

页数：19

共 27 条

[1]

BOZIO R, 1977, J CHEM PHYS, V67, P3864, DOI 10.1063/1.435421

[2] INFLUENCE OF INTER-MOLECULAR CHARGE-TRANSFER INTERACTION ON SOLUTION AND SOLID-STATE INFRARED-SPECTRA OF 7,7,8,8-TETRACYANOQUINODIMETHANE (TCNQ) ALKALINE-SALTS [J].