EXCIMER INTERACTIONS IN POLY(ACENAPHTHALENE) DIADS

被引：6

作者：

SCHOLES, GD

GHIGGINO, KP

机构：

[1] School of Chemistry, University of Melbourne, Parkville

来源：

CHEMICAL PHYSICS LETTERS | 1992年 / 188卷 / 1-2期

基金：

澳大利亚研究理事会;

关键词：

D O I：

10.1016/0009-2614(92)85103-H

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Excited-state semiempirical calculations of excimer interactions in model poly(acenaphthalene) diads are presented. In contrast to previous ground-state molecular modelling, significant excimer interaction was detected in both of the stereoisomers investigated. For the threo-disyndiotactic diad the excimer emission maximum is expected to be bathochromically shifted by approximately 6599 cm-1 from the monomer emission. The shift for the threo-diisotactic diad was calculated to be 5132 cm-1. It is concluded that nearest-neighbour excimer interactions should contribute to the complexity of poly(acenaphthalene) photophysics.

引用

页码：140 / 144

页数：5

共 22 条

[1]

[Anonymous], 1970, PHOTOPHYSICS AROMATI

[2] ENERGY OF EXCIMER LUMINESCENCE .I. RECONSIDERATION OF EXCIMER PROCESSES [J].