ORGANOMETAL COMPOUNDS OF LANTHANOIDS .74. TRIS(METHYLCYCLOPENTADIENYL) COMPLEXES OF LANTHANOIDS

被引：35

作者：

SCHUMANN, H

GLANZ, M

HEMLING, H

机构：

[1] Institut für Anorganische, Analytische Chemie der Technischen Universität Berlin, W-1000 Berlin 12

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 445卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)80220-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

LnCl3 (Ln = La, Sm, Tb) reacts with Na(C5Me4H) in THF to yield the homoleptic complexes Ln(C5Me4H), (1: Ln = La; 2: Ln = Sm; 3: Ln = Tb). The crystals of 3 are rhomboedric, space group R3BAR with a = 1053.5(5) pm, alpha = 95.04(3)-degrees, V = 1153.2(7).10(-30) m3 and Z = 2. Least-squares refinement' on the basis of 392 reflections (F(o) > 4sigma(F(o))) led to a final R value of 0.0266.

引用

页码：C1 / C3

页数：3

共 21 条

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