A NEW NMR TECHNIQUE FOR MEASURING THE GROUND-STATE POPULATIONS OF FORMATE ESTERS - POLAR APROTIC-SOLVENTS FAVOR THE S-CIS (E)-ISOMER OF TERT-BUTYL FORMATE

被引：16

作者：

JUNG, ME

GERVAY, J

机构：

[1] Department of Chemistry and Biochemistry, University of California, Los Angeles

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 33期

关键词：

D O I：

10.1016/S0040-4039(00)97706-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new NMR technique for measuring the conformational population of t-butyl formate in a rapidly equilibrating mixture (3JCH averaging) has been developed and used to show that polar aim)tic solvents favor the E-isomer. © 1990.

引用

页码：4685 / 4688

页数：4

共 17 条

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