PREDISSOCIATION OF OXYGEN IN THE B3-SIGMA-U-STATE

被引：26

作者：

CHIU, SSL

CHEUNG, ASC

FINCH, M

JAMIESON, MJ

YOSHINO, K

DALGARNO, A

PARKINSON, WH

机构：

[1] UNIV GLASGOW,DEPT COMP SCI,GLASGOW G12 8QQ,SCOTLAND

[2] UNIV HONG KONG,DEPT CHEM,HONG KONG,HONG KONG

[3] HARVARD SMITHSONIAN CTR ASTROPHYS,CAMBRIDGE,MA 02138

来源：

JOURNAL OF CHEMICAL PHYSICS | 1992年 / 97卷 / 03期

关键词：

D O I：

10.1063/1.463165

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The predissociation linewidths and level shifts of vibrational levels of three oxygen isotopic molecules O-16(2), (OO)-O-16-O-18, and O-18(2) arising from the interactions of the B (3)SIGMA(u)- state with the four repulsive states (5)PI(u), (3)SIGMA(u)+, (3)PI(u), and (1)PI(u) been calculated. A set of parameters characterizing these interactions has been determined. Good agreement between calculated and experimental predissociation widths and shifts has been obtained for all the three isotopic molecules.

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页码：1787 / 1792

页数：6

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