DECOMPOSITION OF DIHYDROARTEMISITENE ON SILICA-GEL

被引：14

作者：

ELFERALY, FS ^{[1
]}

AYALP, A ^{[1
]}

ALYAHYA, MA ^{[1
]}

MCPHAIL, DR ^{[1
]}

MCPHAIL, AT ^{[1
]}

机构：

[1] DUKE UNIV,PAUL M GROSS CHEM LAB,DEPT CHEM,DURHAM,NC 27706

来源：

JOURNAL OF NATURAL PRODUCTS | 1990年 / 53卷 / 04期

关键词：

D O I：

10.1021/np50070a020

中图分类号：

Q94 [植物学];

学科分类号：

071001 ;

摘要：

Dihydroartemisitene [5], obtained by reducing its hydroperoxy analogue with triphenylphosphine, was found to undergo isomerization to the keto-aldehyde 6 when chromatographed on Si gel. X-ray crystallographic analysis established the structure of each compound. © 1990, American Chemical Society. All rights reserved.

引用

页码：920 / 925

页数：6

共 6 条

[1] MARINE NATURAL-PRODUCTS
FAULKNER, DJ
[J]. NATURAL PRODUCT REPORTS, 1988, 5 (06) : 613 - 663
[2] HETEROCYCLES FROM THE MARINE SPONGE XESTOSPONGIA SP
QUINOA, E
KHO, E
MANES, LV
CREWS, P
BAKUS, GJ
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (22) : 4260 - 4264
[3] ANTITUMOR CYCLIC PEROXIDES FROM THE SPONGE PLAKORTIS-LITA
SAKEMI, S
HIGA, T
ANTHONI, U
CHRISTOPHERSEN, C
[J]. TETRAHEDRON, 1987, 43 (01) : 263 - 268
[4] SILVERSTEIN RM, 1981, SPECTROMETRIC IDENTI, P263
[5] SILVERSTEIN RM, 1981, SPECTROMETRIC IDENTI, P225
[6] WELLS RJ, 1976, TETRAHEDRON LETT, P2637

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