PALLADIUM-CATALYZED REDUCTION OF AN ALLYLIC AMINE - A FORMAL ACCESS TO BOTH DIASTEREOISOMERS OF CYCLOPENTENYL GLYCINE

被引:16
作者
BOURGEOISCURY, A
DOAN, D
GORE, J
机构
[1] Laboratoire de Chimie Organique 1, associé au CNRS, Université Claude Bernard, 69622 Villeurbanne, 43 Bd du
关键词
D O I
10.1016/S0040-4039(00)91600-9
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The easily accessible bicyclic amines 3 (exo or endo) are regioselectively transformed to the methyl esters of the diastereoisomers (1c or 1d) of N-benzyl cyclopentenyl glycine by reaction with hydride donors (mainly NaBH3CN) in the presence of a palladium(0) catalyst.
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页码:1277 / 1280
页数:4
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