OXIDATIVE DEHYDROGENATION OF ISOBUTYRIC ACID ON H4PVMO11O40, NAXH4-XPVMO11O40 AND CUYH4-2YPVMO11O40 HETEROPOLYACID CATALYSTS SUPPORTED ON SILICA

被引：28

作者：

ABOUKAIS, A ^{[1
]}

GHOUSSOUB, D ^{[1
]}

BLOUETCRUSSON, E ^{[1
]}

RIGOLE, M ^{[1
]}

GUELTON, M ^{[1
]}

机构：

[1] UNIV LITTORAL,CATALYSE & ENVIRONNEMENT LAB,F-62100 CALAIS,FRANCE

来源：

APPLIED CATALYSIS A-GENERAL | 1994年 / 111卷 / 02期

关键词：

DEHYDROGENATION; HETEROPOLYACID SILICA; ISOBUTYRIC ACID DEHYDROGENATION; METHACRYLIC ACID;

D O I：

10.1016/0926-860X(94)85045-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The oxidative dehydrogenation of isobutyric acid (IBA) to methacrylic acid (MAA) was studied over the heteropolyacid H4PVMo11O40 and the acidic salts NaxH4-xPVMo11O40 and CuyH4-2yPVMO11O40, supported on silica, as catalysts. The presence of copper as counter-cations in the heteropoly compounds increases the activity and the selectivity to MAA. This increase is probably due to the simultaneous presence in the solids of Bronsted acidity and oxygen vacancies with an adequate ratio. These latter sites can more easily be obtained in the presence of Cu2+ and V4+ than with Na+ counter-ions in the catalysts.

引用

页码：109 / 118

页数：10

共 29 条

[1] ABOUKAIS A, UNPUB
[2] EFFECTS OF CATIONS INTRODUCED INTO 12-MOLYBDOPHOSPHORIC ACID ON THE CATALYST PROPERTIES
AI, M
[J]. APPLIED CATALYSIS, 1982, 4 (03): : 245 - 256
[3] 12-HETEROPOLYMOLYBDATES AS CATALYSTS FOR VAPOR-PHASE OXIDATIVE DEHYDROGENATION OF ISOBUTYRIC ACID .2. GROUP-IB, GROUP-IIB, GROUP-IIIB, AND VIII-METAL SALTS
AKIMOTO, M
SHIMA, K
IKEDA, H
ECHIGOYA, E
[J]. JOURNAL OF CATALYSIS, 1984, 86 (01) : 173 - 186
[4] LOW-TEMPERATURE COPPER INTERCALATION IN SODIUM VANADIUM OXIBRONZE - PREPARATION AND CHARACTERIZATION
BALLIVETTKATCHENKO, D
DELAHAY, G
PARIZE, JL
SAVARIAULT, JM
GALY, J
[J]. CHEMISTRY OF MATERIALS, 1993, 5 (08) : 1157 - 1161
[5] BLOUETCRUSSON E, 1994, THESIS U LILLE FRANC
[6] STEREOCHEMISTRY OF HYDRATED COPPER(II) IONS ON INTERLAMELLAR SURFACES OF LAYER SILICATES - ELECTRON-SPIN RESONANCE STUDY
CLEMENTZ, DM
PINNAVAIA, TJ
MORTLAND, MM
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1973, 77 (02) : 196 - 200
[7] BEHAVIOR OF COPPER(II) ION-PAIRS IN CU2PMO11VO40.21H2O CATALYSTS - ELECTRON-PARAMAGNETIC RESONANCE STUDY
CRUSSONBLOUET, E
ABOUKAIS, A
AISSI, CF
GUELTON, M
[J]. CHEMISTRY OF MATERIALS, 1992, 4 (06) : 1129 - 1131
[8] ELECTRON-PARAMAGNETIC RESONANCE INVESTIGATIONS OF PHOTOSENSITIVE TRANSITION-METAL OXALATES - COPPER-DOPED K2PD(C2O4)2.2H2O
EACHUS, RS
MCDUGLE, WG
[J]. INORGANIC CHEMISTRY, 1973, 12 (07) : 1561 - 1566
[9] Ernst V., 1987, CATAL TODAY, V1, P167
[10] GHOUSSOUB D, 1990, THESIS U LILLE FRANC

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