THE LINEAR MNII COMPLEX MN3(5-NO2-SALIMH)2(OAC)4 PROVIDES AN ALTERNATIVE STRUCTURE TYPE FOR THE CARBOXYLATE SHIFT IN PROTEINS

被引：19

作者：

BALDWIN, MJ ^{[1
]}

KAMPF, JW ^{[1
]}

PECORARO, VL ^{[1
]}

机构：

[1] UNIV MICHIGAN,DEPT CHEM,ANN ARBOR,MI 48109

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 23期

关键词：

D O I：

10.1039/c39930001741

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title complex {where 5-NO2-salimH-2 = 4-[2-(5-NO2-salicylideneimine)ethyl]imidazole} has been structurally characterized and is the first mu-phenolato, mu-carboxylato-O, mu-carboxylato-O,O' type model for the 'carboxylate shift' in polymanganese and polyiron enzymes.

引用

页码：1741 / 1743

页数：3

共 18 条

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