SOL-GEL KINETICS .2. CHEMICAL SPECIATION MODELING

被引：85

作者：

KAY, BD

ASSINK, RA

机构：

[1] Sandia Natl Lab, Albuquerque, NM,, USA, Sandia Natl Lab, Albuquerque, NM, USA

来源：

JOURNAL OF NON-CRYSTALLINE SOLIDS | 1988年 / 104卷 / 01期

关键词：

CHEMICAL REACTIONS - Reaction Kinetics - SILICON AND ALLOYS - STATISTICAL METHODS;

D O I：

10.1016/0022-3093(88)90189-5

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

We present an exact theoretical kinetic formalism which specifically treats the temporal evolution of the various chemical functional groups about a specific silicon atom undergoing concurrent hydrolysis and condensation reactions. This formalism is applied to the chemical kinetics of a typical sol-gel reaction system. We also present a simplified statistical reaction model which reduces the number of chemically distinct rate coefficients necessary to describe the kinetics from 165 to 3. Experimental results which support this statistical model are also presented.

引用

页码：112 / 122

页数：11

共 18 条

[1] Artaki I., 1984, Materials Letters, V2, P448, DOI 10.1016/0167-577X(84)90160-5
[2] NMR AND RAMAN-STUDY OF THE HYDROLYSIS REACTION IN SOL-GEL PROCESSES
ARTAKI, I
BRADLEY, M
ZERDA, TW
JONAS, J
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1985, 89 (20) : 4399 - 4404
[3] SI-29 NMR-STUDY OF THE INITIAL-STAGE OF THE SOL-GEL PROCESS UNDER HIGH-PRESSURE
ARTAKI, I
SINHA, S
IRWIN, AD
JONAS, J
[J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 1985, 72 (2-3) : 391 - 402
[4] SOL-GEL KINETICS .1. FUNCTIONAL-GROUP KINETICS
ASSINK, RA
KAY, BD
[J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 1988, 99 (2-3) : 359 - 370
[5] ASSINK RA, 1984, BETTER CERAMICS CHEM, P301
[6] ASSINK RA, UNPUB J NONCRYST SOL
[7] SOL-GEL TRANSITION IN SIMPLE SILICATES .2.
BRINKER, CJ
KEEFER, KD
SCHAEFER, DW
ASSINK, RA
KAY, BD
ASHLEY, CS
[J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 1984, 63 (1-2) : 45 - 59
[8] Brinker CJ, 1986, BETTER CERAMICS CHEM
[9] BRINKER CJ, 1984, BETTER CERAMICS CHEM
[10] ENGELHARDT H, 1975, Z CHEM, V14, P109

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