14N NUCLEAR QUADRUPOLE COUPLING CONSTANTS OF ORGANIC NITRILES

被引:29
作者
COLLIGIA.A
GUIBE, L
HAIGH, PJ
LUCKEN, EAC
机构
[1] Istituto di Chimica Fisica, dell'Università, Pisa, Via Risorgimento
[2] Institut d'Electronique Laboratoire associé au C.N.R.S., Orsay (S. et O.)
[3] Florida Presbyterian College, St. Petersburg, FL
[4] Cyanamid European Research Institute, Geneva
关键词
D O I
10.1080/00268976800100081
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The 14N quadrupole coupling constants of a number of saturated organic nitriles have been determined by pure quadrupole resonance spectroscopy. The significance of these results together with those previously obtained for the nitrile group to the problem of long-range interactions in saturated molecules is discussed and it is shown that such interactions can for this system be at least as important as those produced by the more familiar conjugation. © 1968 Taylor and Francis Group, LLC.
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页码:89 / &
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