Morphological Control of Electropolymerization on Porous Substrates

被引：10

作者：

Cahalane, W. ^{[1
]}

Labes, M. M. ^{[1
]}

机构：

[1] Temple Univ, Dept Chem, Philadelphia, PA 19122 USA

来源：

CHEMISTRY OF MATERIALS | 1989年 / 1卷 / 05期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1021/cm00005a011

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Unique morphologies are achieved when pyrrole and 3-methylthiophene are electrochemically polymerized on two porous substrates, Nuclepore and stainless steel mesh. Polypyrrole forms highly oriented tubular whiskers on Nuclepore with striations along the direction of growth having conductivities between 2000 and 3000 S cm(-1), higher than those observed in typical preparations of polypyrrole films. On the other hand, poly(3-methylthiophene) forms whiskers with an interesting spiral morphology, having relatively poor conductivities.

引用

页码：519 / 522

页数：5

共 17 条

[1]

BI XT, 1985, MAKROMOL CHEM, V186, P1101

[2] ELECTRONICALLY CONDUCTIVE POLYMER FIBERS WITH MESOSCOPIC DIAMETERS SHOW ENHANCED ELECTRONIC CONDUCTIVITIES [J].