THE PREPARATION AND CRYSTAL-STRUCTURES OF SODIUM AND POTASSIUM PENTAMETHYLCYCLOPENTADIENYL PYRIDINE SOLVATES

被引:97
作者
RABE, G [1 ]
ROESKY, HW [1 ]
STALKE, D [1 ]
PAUER, F [1 ]
SHELDRICK, GM [1 ]
机构
[1] UNIV GOTTINGEN,INST ANORGAN CHEM,TAMMANNSTR 4,W-3400 GOTTINGEN,GERMANY
关键词
D O I
10.1016/0022-328X(91)83082-F
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The compounds (C5Me5)Na.3py (1) and (C5Me5)K.2py (2) have been prepared and their crystal structures determined at low temperatures. The crystal structure of 1 exhibits a three-legged stool monomer of composition (C5Me5)Na.3py, whereas 2 has a linear zig-zag chain structure of composition [(C5Me5)K.2py]infinity.
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页码:11 / 19
页数:9
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