BENZENEHEXATHIOL AS A TEMPLATE RIM FOR A GOLDEN WHEEL - SYNTHESIS AND STRUCTURE OF [(CSAU(PPH3))6]

被引：64

作者：

YIP, HK ^{[1
]}

SCHIER, A ^{[1
]}

RIEDE, J ^{[1
]}

SCHMIDBAUR, H ^{[1
]}

机构：

[1] TECH UNIV MUNICH,INST ANORGAN CHEM,LICHTENBERGSTR 4,D-85747 GARCHING,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1994年 / 15期

关键词：

D O I：

10.1039/dt9940002333

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of benzenehexathiol, C6(SH)6, with [Au(PPh3)Cl] in the presence of triethylamine gave the hexanuclear gold(I) compound [{CSAu(PPh3)}6] whose structure has been determined; the hexagon of the central benzene carbon atoms is surrounded by a hexagon of sulfur atoms, followed by a hexagon of gold atoms and the wheel-like structure is completed by six peripheral phosphine ligands with interlocked aryl groups.

引用

页码：2333 / 2334

页数：2

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