ELECTROCHEMICAL PROPERTY AND FORMATION OF THE CATION RADICAL AND DICATION OF DINAPHTHO[1,8-B,C]-1,5-DITHIOCIN

被引：23

作者：

FUJIHARA, H

CHIU, JJ

FURUKAWA, N

机构：

来源：

CHEMISTRY LETTERS | 1990年 / 12期

关键词：

D O I：

10.1246/cl.1990.2217

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new symmetrical dithio peri-bridged naphthalene, dinaphthol[1,8-b,c]-1,5-dithiocin (1) has been synthesized. The cyclic voltammogram of 1 showed one reversible oxidation peak. ESR spectrum of the concd H2SO4 solution of 1 showed the formation of the cation radical. The formation of the dictation of 1 was observed in the reaction of the corresponding monosulfoxide with concd D2SO4 by both high-field H-1 and C-13 NMR spectroscopy.

引用

收藏

页码：2217 / 2220

页数：4

相关论文

共 14 条

[1] STRUCTURES OF THE RADICAL CATION AND DICATION FROM OXIDATION OF 1,6-DIAZABICYCLO[4.4.4]TETRADECANE [J].

ALDER, RW ;

ORPEN, AG ;

WHITE, JM .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (14) :949-951

[2]

ALDER RW, 1982, CHEM AMINO NITROSO N, pCH18

[3] STABILIZATION OF OXIDIZED SULFUR CENTERS IN ORGANIC SULFIDES - RADICAL CATIONS AND ODD-ELECTRON SULFUR-SULFUR BONDS [J].

ASMUS, KD .

ACCOUNTS OF CHEMICAL RESEARCH, 1979, 12 (12) :436-442

[4]

BARD AJ, 1976, ADV PHYSICAL ORGANIC, V13, P155

[5]

BARRY G, 1966, B SOC CHIM FR, P2510

[6] TRANS-ANNULAR SULFUR-SULFUR INTERACTION IN 3,7,9-TRITHIABICYCLO[3.3.1]NONANE AS A NEW CYCLIC TRIS-SULFIDE - QUEST FOR THE INTRABRIDGED DITHIA DICATION [J].

FUJIHARA, H ;

AKAISHI, R ;

FURUKAWA, N .

TETRAHEDRON LETTERS, 1989, 30 (33) :4399-4402

[7] 1,5-DISELENACYCLO-OCTANE - SYNTHESIS AND THE 1ST ISOLATION OF THE DISELENIDE PF6-SALT [R2SE+-SE+R2] [J].

FUJIHARA, H ;

AKAISHI, R ;

ERATA, T ;

FURUKAWA, N .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (23) :1789-1790

[8]

FUJIHARA H, 1989, J MOL STRUC-THEOCHEM, V186, P261

[9] SULFUR SULFUR LONE PAIR AND SULFUR NAPHTHALENE INTERACTIONS IN NAPHTHO[1,8-B,C]-1,5-DITHIOCIN [J].

GLASS, RS ;

ANDRUSKI, SW ;

BROEKER, JL ;

FIROUZABADI, H ;

STEFFEN, LK ;

WILSON, GS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (11) :4036-4045

[10] SYNTHESIS OF SOME DIPHENYL AND TRIPHENYL DERIVATIVES OF ANTHRACENE AND NAPHTHALENE [J].

HOUSE, HO ;

CAMPBELL, WJ ;

KOEPSELL, DG .

JOURNAL OF ORGANIC CHEMISTRY, 1972, 37 (07) :1003-&