DIMETHYL-SULFOXIDE PHASE C-H BOND-DISSOCIATION ENERGIES FOR PHENALENE AND BENZANTHRENE

被引：20

作者：

BAUSCH, MJ

GOSTOWSKI, R

JIRKA, G

SELMARTEN, D

WINTER, G

机构：

[1] Department of Chemistry and Biochemistry, Southern Illinois University—Carbondale, Illinois 62901-4409, Carbondale

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 23期

关键词：

D O I：

10.1021/jo00310a002

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

: Comparisons of fluorene, phenalene, and benzanthrene sp3C-H homolytic bond dissociation energy data, data collected with the aid of a cycle that utilizes acid-base and redox data collected in dimethyl sulfoxide solution, indicate that the sp3C-H bonds in phenalene and benzanthrene are about 18 and 16 kcal/mol weaker (in a homolytic sense) than the sp3C-H bond in fluorene. © 1990, American Chemical Society. All rights reserved.

引用

页码：5805 / 5806

页数：2

共 19 条

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