SYNTHESIS AND SPECTROSCOPIC PROPERTIES OF WATER-SOLUBLE CERIUM(III) OR PRASEODYMIUM(III) MONO[TETRA(4-PYRIDYL)-PORPHYRINATE] AND CERIUM(IV) BIS[TETRA(4-PYRIDYL)-PROPHYRINATE]

被引：18

作者：

JIANG, J ^{[1
]}

MACHIDA, K ^{[1
]}

YAMAMOTO, E ^{[1
]}

ADACHI, G ^{[1
]}

机构：

[1] OSAKA UNIV, FAC ENGN, DEPT APPL CHEM, SUITA, OSAKA 565, JAPAN

来源：

CHEMISTRY LETTERS | 1991年 / 11期

关键词：

D O I：

10.1246/cl.1991.2035

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Water-soluble lanthanoid mono- and bisporphyrins, Ln(TPyP)acac (Ln = Ce, Pr) and Ln(TPyP)2 (Ln = Ce) [TPyP = tetra(4-pyridyl)-porphyrin, acac = acetylacetone] were synthesized by refluxing Ln(acac)3 . nH2O (Ln = Ce, Pr) and H2TPyP in 1,2,4-trichlorobenzene. The complexes were characterized based on UV/vis absorption and H-1-NMR spectra, respectively.

引用

页码：2035 / 2038

页数：4

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