ONE-POT CONVERSION OF PRIMARY ALCOHOLS TO ALPHA-OXYGENATED ALKANALS WITH TEMPO IN COMBINATION WITH MOLECULAR-OXYGEN AND RUTHENIUM COMPLEX

被引：50

作者：

INOKUCHI, T

NAKAGAWA, K

TORII, S

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Okayama University, Okayama

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 18期

关键词：

D O I：

10.1016/0040-4039(95)00519-I

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of primary alcohols with an oxidizing system composed of 4-BzOTEMPO (2 equiv.), RuCl2(PPh(3))(3) as a catalyst, and molecular oxygen leads to concomitant oxidation and substitution, giving the corresponding or-oxygenated alkanals. Similar reaction of secondary alcohols terminates at the stage of oxidation of hydroxyl group, forming the ketones, selectively.

引用

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页码：3223 / 3226

页数：4

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