AMORPHOUS ALLOY CATALYSIS .2. EFFECTS OF DEHYDROGENATION OF 2-PROPANOL ON THE STRUCTURE AND CATALYTIC ACTIVITY OF AN AMORPHOUS COPPER-ZIRCONIUM ALLOY SAMPLE

被引:12
作者
KATONA, T
HEGEDUS, Z
KOPASZ, C
MOLNAR, A
BARTOK, M
机构
[1] ATTILA JOZSEF UNIV, DEPT ORGAN CHEM, H-6701 SZEGED, HUNGARY
[2] AGMI, INST MAT TESTING & QUAL CONTROL, BUDAPEST, HUNGARY
[3] CSEPEL IRON & MET WORKS, BUDAPEST, HUNGARY
关键词
Amorphous Cu-Zr alloy; dehydrogenation of 2-propanol; surface enrichment in copper;
D O I
10.1007/BF00765178
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The effects of the dehydrogenation of 2-propanol on the structure of an amorphous Cu61Zr39 alloy sample were analysed by means of scanning electron microscopy (SEM), energy dispersive X-ray microanalysis (EDAX), and Auger electron spectroscopy (AES). The inner and outer sides of the as-received amorphous ribbon differed considerably, indicating copper and zirconium enrichment, respectively. During a 24 h reaction dramatic changes in surface morphology and a substantial copper enrichment took place on both sides, resulting in very similar surfaces. © 1990 J.C. Baltzer A.G. Scientific Publishing Company.
引用
收藏
页码:361 / 368
页数:8
相关论文
共 30 条
[1]   AMMONIA-SYNTHESIS OVER A NOVEL CATALYST PREPARED FROM AN AMORPHOUS FE91ZR9 PRECURSOR [J].
ARMBRUSTER, E ;
BAIKER, A ;
BARIS, H ;
GUNTHERODT, HJ ;
SCHLOGL, R ;
WALZ, B .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (04) :299-301
[2]   SUPPORTED PALLADIUM CATALYST PREPARED FROM AMORPHOUS PALLADIUM-ZIRCONIUM [J].
BAIKER, A ;
GASSER, D .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1989, 85 :999-&
[3]   NOVEL HYDROGENATION CATALYST PREPARED FROM AN AMORPHOUS CU70ZR30 PRECURSOR [J].
BAIKER, A ;
BARIS, H ;
GUNTHERODT, HJ .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (12) :930-932
[4]   AMMONIA-SYNTHESIS OVER SUPPORTED IRON CATALYST PREPARED FROM AMORPHOUS IRON ZIRCONIUM PRECURSOR .1. BULK STRUCTURAL AND SURFACE CHEMICAL-CHANGES OF PRECURSOR DURING ITS TRANSITION TO THE ACTIVE CATALYST [J].
BAIKER, A ;
SCHLOGL, R ;
ARMBRUSTER, E ;
GUNTHERODT, HJ .
JOURNAL OF CATALYSIS, 1987, 107 (01) :221-231
[5]   A HIGHLY-ACTIVE CATALYST FOR THE OXIDATION OF CARBON-MONOXIDE, PREPARED FROM AMORPHOUS PALLADIUM ZIRCONIUM ALLOY [J].
BAIKER, A ;
GASSER, D ;
LENZNER, J .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (23) :1750-1751
[6]  
BAIKER A, 1989, FARADAY DISCUSS CHEM, V87
[7]  
BAIKER A, 1988, 9TH P INT C CAT CALG, V4, P1928
[8]   SUPPORTED COPPER-CATALYSTS IN THE SYNTHESIS OF METHANOL - N2O-TITRATIONS [J].
DENISE, B ;
SNEEDEN, RPA ;
BEGUIN, B ;
CHERIFI, O .
APPLIED CATALYSIS, 1987, 30 (02) :353-363
[9]   ON THE DETERMINATION OF COPPER SURFACE-AREA BY REACTION WITH NITROUS-OXIDE [J].
EVANS, JW ;
WAINWRIGHT, MS ;
BRIDGEWATER, AJ ;
YOUNG, DJ .
APPLIED CATALYSIS, 1983, 7 (01) :75-83
[10]   HYDROGENATION OF CARBON-DIOXIDE OVER COPPER-ZIRCONIA CATALYSTS PREPARED BY INSITU ACTIVATION OF AMORPHOUS COPPER-ZIRCONIUM ALLOY [J].
GASSER, D ;
BAIKER, A .
APPLIED CATALYSIS, 1989, 48 (02) :279-294