CALIXARENES AS HOSTS IN AQUEOUS-MEDIA - INCLUSION COMPLEXATION OF FERROCENE DERIVATIVES BY A WATER-SOLUBLE CALIX[6]ARENE

被引：73

作者：

ZHANG, L

MACIAS, A

LU, TB

GORDON, JI

GOKEL, GW

KAIFER, AE

机构：

[1] UNIV MIAMI,DEPT CHEM,CORAL GABLES,FL 33124

[2] WASHINGTON UNIV,SCH MED,DEPT MOLEC BIOL & PHARMACOL,ST LOUIS,MO 63110

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 12期

关键词：

D O I：

10.1039/c39930001017

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complexation of trimethyl(ferrocenylmethyl)ammonium hexafluorophosphate 1.(BF6), heptyldimethyl(ferrocenylmethyl)ammonium bromide 2.(Br) and ferrocenylmethanol 3 by a sulfonated calix[6]arene host was investigated in aqueous media using electrochemical and H-1 NMR spectroscopic techniques; the binding interactions between the calixarene host and the surveyed guests are similar to those operating in the complexation of organic compounds by cyclodextrin or cyclophane hosts in aqueous media.

引用

页码：1017 / 1019

页数：3

共 14 条

[1]

ANDREETI GD, 1991, INCLUSION COMPOUNDS, V4

[2] MOLECULAR RECOGNITION .3. POLAR HOST GUEST INTERACTIONS - SOLUBILIZATION OF SOME POLAR COMPOUNDS WITH LIPOPHILIC CALIX[6]ARENES CONTAINING POLAR GROUPS IN APOLAR MEDIA [J].