A NOVEL SYNTHESIS OF ALPHA-HALONAPHTHALENES AND BETA-HALONAPHTHALENES VIA REGIOSELECTIVE RING CLEAVAGE OF ARYL(GEM-DIHALOCYCLOPROPYL)METHANOLS AND ITS APPLICATION TO TOTAL SYNTHESIS OF LIGNAN LACTONES, JUSTICIDIN-E AND TAIWANIN-C

被引：31

作者：

SEKO, S ^{[1
]}

TANABE, Y ^{[1
]}

SUZUKAMO, G ^{[1
]}

机构：

[1] SUMITOMO CHEM CO LTD,TAKATSUKI RES LAB,TAKATSUKI,OSAKA 569,JAPAN

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 47期

关键词：

D O I：

10.1016/S0040-4039(00)97197-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Acid treatment of two types of aryl(gem-dihalocyclopropyl)methanols (ADCM) 1 gave α- and β-halonaphthalenes in good yields with excellent selectivity. With the new method used as the key step, the two title natural lignan lactones were synthesized in seven steps. © 1990.

引用

页码：6883 / 6886

页数：4

共 12 条

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