A PYROLYSIS JET SPECTROSCOPIC STUDY OF THE ROTATIONALLY RESOLVED ELECTRONIC-SPECTRUM OF DICHLOROCARBENE

被引：82

作者：

CLOUTHIER, DJ ^{[1
]}

KAROLCZAK, J ^{[1
]}

机构：

[1] ADAM MICKIEWICZ UNIV,INST PHYS,QUANTUM ELECTR LAB,PL-60780 POZNAN,POLAND

来源：

JOURNAL OF CHEMICAL PHYSICS | 1991年 / 94卷 / 01期

关键词：

D O I：

10.1063/1.460378

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The rotationally resolved, gas phase vibronic spectrum of dichlorocarbene has been recorded using the technique of pyrolysis jet spectroscopy. The rovibronic analysis has established the band origin of the A approximately 1B1-X approximately 1A1 electronic transition to be at 17 255.67 cm-1. The observed vibrational frequencies in the ground and excited states are very close to published values from matrix isolation data. The excited state structure has a 131.4-degrees CICCI angle and a 1.652 angstrom CCI bond length.

引用

页码：1 / 10

页数：10

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