CONVERSION OF 1-(OMEGA-ALKYNYL)-1,2-PROPADIENYL SULFIDES TO BICYCLIC DIENONES BY THE USE OF IRON CARBONYL COMPLEX

被引：23

作者：

NARASAKA, K

SHIBATA, T

机构：

来源：

CHEMISTRY LETTERS | 1994年 / 02期

关键词：

D O I：

10.1246/cl.1994.315

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1-(omega-Alkenyl)-1,2-propadienyl sulfide reacts with Fe(CO)(4)(NMe(3)) under photo irradiation conditions and a cyclized and carbonylated eta(3)-allyl mononuclear iron complex is isolated. On the other hand, the reaction of 1-(omega-alkynyl)-1,2-propadienyl sulfides and Fe(CO)(4)(NMe(3)) also proceeds by photo irradiation to give various bicyclic dienones through the eta(3)-allyl iron complex.

引用

收藏

页码：315 / 318

页数：4

相关论文

共 20 条

[1] ORGANIC SYNTHESES VIA TRANSITION-METAL COMPLEXES .19. BETA-METHYLENECYCLOPENTENONES VIA IRON CARBONYL-INDUCED [2 + 2 + 1] CYCLOADDITION OF ALKYNES TO ALLENES AND CARBON-MONOXIDE [J].

AUMANN, R ;

WEIDENHAUPT, HJ .

CHEMISCHE BERICHTE-RECUEIL, 1987, 120 (01) :23-27

[2] COORDINATION CHEMISTRY OF ALLENES [J].

BOWDEN, FL ;

GILES, R .

COORDINATION CHEMISTRY REVIEWS, 1976, 20 (01) :81-106

[3]

DAVIS RE, 1968, J CHEM SOC CHEM COMM, P248

[4] [2+2] CYCLOADDITION REACTION BETWEEN ALLENYL SULFIDES AND ELECTRON DEFICIENT OLEFINS PROMOTED BY LEWIS-ACIDS [J].

HAYASHI, Y ;

NIIHATA, S ;

NARASAKA, K .

CHEMISTRY LETTERS, 1990, (11) :2091-2094

[5] SYNTHESIS AND REACTIONS OF TETRACARBONYLIRON AND TRICARBONYLIRON COMPLEXES OF ALPHA,BETA-UNSATURATED KETONES [J].

HOWELL, JAS ;

JOSTY, PL ;

JOHNSON, BFG ;

LEWIS, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1972, 39 (02) :329-&

[6] ORGANOSULFUR DERIVATIVES OF METAL CARBONYLS .1. ISOLATION OF 2 ISOMERIC PRODUCTS IN REACTION OF TRIIRON DODECACARBONYL WITH DIMETHYL DISULFIDE [J].

KING, RB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1962, 84 (12) :2460-&

[7]

KNOLKER HJ, 1992, SYNLETT, P1002

[8] STRUCTURES OF 2 COMPLEXES DERIVED FROM AN ALLENIC ESTER AND DIIRON ENNEACARBONYL - A SYNTHETIC ROUTE TO 2-CARBALCOXY BUTADIENE COMPLEXES [J].

MARTINA, D ;

BRION, F ;

DECIAN, A .

TETRAHEDRON LETTERS, 1982, 23 (08) :857-860

[9] INTERACTION OF CUMULENE SYSTEMS WITH ORGANOMETALLIC PI-COMPLEXES .4. NOVEL PI-ALLYL COMPLEXES OBTAINED FROM REACTIONS OF ALLENE WITH IRON AND COBALT CARBONYLS [J].

NAKAMURA, A .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1966, 39 (03) :543-+

[10] REACTIONS OF 1,2-PROPADIENYL SULFIDES WITH ALDEHYDES AND ACETALS CATALYZED BY BF3.OET2 [J].

NARASAKA, K ;

SHIBATA, T ;

HAYASHI, Y .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1992, 65 (10) :2825-2830