ENZYMES AS REAGENTS IN ORGANIC-CHEMISTRY - TRANSKETOLASE-CATALYZED SYNTHESIS OF D-[1,2-(C-13)2]XYLULOSE

被引：24

作者：

DEMUYNCK, C

BOLTE, J

HECQUET, L

SAMAKI, H

机构：

[1] Laboratoire de Chimie Organique Biologique (U.R.A. 485 du C.N.R.S.), Université Blaise Pascal

来源：

CARBOHYDRATE RESEARCH | 1990年 / 206卷 / 01期

关键词：

D O I：

10.1016/0008-6215(90)84008-I

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Oxidation of commercial dl-[2,3-13C2]serine by d-amino acid oxidase gave [2,3-13C2]hydroxypyruvate, the condenstion of which with d-glyceraldehyde, catalysed by transketolase (partially purified from spinach leaves), gave d-threo-[1,2-13C2]pentulose (d-[1,2-13C2]xylulose), which was studied by 13C-n.m.r. spectroscopy. © 1990.

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页码：79 / 85

页数：7

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